Van de Graaff

A Van de Graaff generator is an electrostatic generator which uses a moving belt to accumulate electric charge on a hollow metal globe on the top of an insulated column, creating very high electric potentials. It produces very high voltage direct current (DC) electricity at low current levels.
     

When the Van de Graaff generator starts charging, it transfers the charge to the person who is touching it. Since the person's hair follicles are getting charged to the same potential, they try to repel each other. This is why the hair actually stands up. It would not make a difference if the polarity of the Van de Graaff generator were reversed. As long as the person is insulated, the charge will build up (assuming, of course, that the hair is clean and dry).